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Bromine
Br 35

Bromine

Bromine is a chemical element; it has symbol Br and atomic number 35. It is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly colored vapor. Its properties are intermediate between those of chlorine and iodine. Bromine is significantly less abundant in the crust than fluorine or chlorine. It is primarily used in flame retardants (now increasingly regulated), pharmaceuticals, and as a catalyst in some chemical processes.

Halogen a62929
Atomic number 35Z
Atomic mass 79.904u
Valence e⁻ 7
Electron config. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5
Density
3.1g/cm³
Melting point
-7°C
Crustal abundance
2.4ppm
Annual production
Recycling rate
Mainly extracted from seawater and brine

Why This Element

Bromine is rare yet strategic: historically the primary fire retardant for electronics and furniture (until regulations restricted polybrominated diphenyl ethers), and irreplaceable in oil and gas well drilling fluids. Its unique liquid state among nonmetals enables specialized chemical reactions and analytical techniques.

Applications

Flame retardantsWater treatmentPhotographic materialsPesticidesPharmaceutical production

Applications in DepthElement & compound uses

Main Uses of the Element

Bromine is one of the only liquid nonmetals at room temperature, with a density of about 3.1028 g/cm³ and a melting point around −7 °C; it is deep red-brown, highly volatile, sharply pungent, and highly toxic. It is extracted mainly from bromides in seawater, enriched by air-blowing or resin processes before conversion into downstream products. Brominated flame retardants are bromine's largest industrial outlet: bromine compounds release bromine radicals that trap combustion chain reactions during burning, widely used in electronics enclosures, building insulation foams, textiles, and automotive interiors, and are an important means of plastics flame retardancy. In dyes and pharmaceuticals, bromine is used to synthesize indigo, disperse dyes, and numerous pharmaceutical intermediates; seawater bromine extraction itself is also a major branch of the marine chemical industry. Historically silver bromide was the core photosensitive material of photographic film, but has shrunk sharply in the digital era. It must be stressed that elemental bromine and its vapor are highly toxic and corrosive, so handling must be done sealed inside a fume hood.

Key Compounds and Their Uses

Sodium bromide NaBr was once used as a sedative; today it mainly serves in oil drilling muds, water treatment, and as a bromide feedstock. Silver bromide AgBr is the photosensitive material of traditional photographic film and paper, decomposing under light to form silver grains that make a latent image; demand has fallen sharply with digital photography but it still survives in specialty films. Potassium bromide KBr is transparent to infrared light and has long served as sample windows and pressed pellets in infrared spectrometry. Lithium bromide LiBr is highly water-soluble and strongly hygroscopic, and is the working fluid of absorption chillers, using waste heat to drive large air-conditioning and refrigeration systems. Brominated flame retardants such as decabromodiphenylethane and tetrabromobisphenol A are the workhorses of plastics and textile flame retardancy. Methyl bromide CH3Br was once a widely used soil fumigant insecticide, phased out under international treaty because it depletes the ozone layer. Hydrobromic acid HBr is used in pharmaceuticals, dyes, and catalyst synthesis.

Element History

Isolated in 1826 by Antoine Jérôme Balard from salt marsh bittern (the mother liquor remaining after salt evaporation) in Montpellier, France. Balard initially thought he had discovered iodide mixed with chlorine; only later did he recognize the distinct reddish-brown liquid as a new element. He named it bromine for its strong odor. Largest deposits are in the Dead Sea and US underground brines.

Related Elements

F · Fluorine Cl · Chlorine I · Iodine At · Astatine Ts · Tennessine

Frequently Asked QuestionsLong-tail Q&A · data-driven

What is the melting point of Bromine?
-7 °C
What is the boiling point of Bromine?
59 °C
What is the density of Bromine?
3.1 g/cm³
What are the atomic number and category of Bromine?
35 · Halogen
Which ore is Bromine mainly extracted from?
brine, seawater
What are the main uses of Bromine?
Bromine is rare yet strategic: historically the primary fire retardant for electronics and furniture (until regulations restricted polybrominated diphenyl ethers), and irreplaceable in oil and gas well drilling fluids. I
Who discovered Bromine and when?
Antoine Jérôme Balard · Ancient (known since antiquity)