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Sulfur
S 16

Sulfur

Sulfur (or sulphur in British English) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur occurs naturally as the pure element and as sulfide and sulfate minerals. It is essential for life, being a component of cysteine, methionine, coenzyme A, and many other biologically important molecules. Industrially, sulfur is primarily consumed for the production of sulfuric acid, which is used widely in chemical synthesis and petroleum refining.

Nonmetal lemon yellow sintered microcrystals
Atomic number 16Z
Atomic mass 32.06u
Valence e⁻ 6
Electron config. 1s2 2s2 2p6 3s2 3p4
Density
2.07g/cm³
Melting point
115°C
Crustal abundance
350.0ppm
Annual production
Recycling rate
Mostly recovered as byproduct of refinery desulfurization

Why This Element

Sulfur is the 10th most abundant element in the universe and plays dual critical roles: as an essential component of proteins (disulfide bonds in cysteine) and as the feedstock for sulfuric acid — the single most important industrial chemical by production volume and value, central to fertilizers, metals processing, and chemical synthesis.

Applications

Sulfuric acidRubber vulcanizationMatches & gunpowderFertilizersPharmaceuticals

Applications in DepthElement & compound uses

Main Uses of the Element

Sulfur is the starting material of sulfuric acid, the “mother of chemicals” of modern industry. Elemental sulfur itself is used in limited quantities, but almost all of it is converted into sulfuric acid before flowing into every corner of industry. Sulfur is roasted or recovered from smelter off-gas to produce sulfuric acid, known as the mother of chemicals and a foundational feedstock for fertilizers, metallurgy, petrochemicals, and light industry. Vulcanization is sulfur's most iconic application: after sulfur is added to natural or synthetic rubber, sulfur atoms form cross-links between polymer chains, turning sticky, soft raw rubber into elastic, wear-resistant, heat-resistant vulcanized rubber; tires, hoses, seals, and shoe soles all depend on this process. In civilian use, sulfur goes into black powder and fireworks, as well as wood preservation, soil amendment, and pesticide fungicides. Historically it also entered sulfuric acid, sulfur soap, and traditional medicine.

Key Compounds and Their Uses

Sulfuric acid H2SO4 is one of the highest-volume chemical products, used to make phosphate and nitrogen fertilizers, as a refining catalyst in the petroleum industry, for pickling steel and extracting uranium and copper in metallurgy, and as the electrolyte in lead-acid batteries. Iron disulfide FeS2 is pyrite, nicknamed fool's gold, traditionally the main ore for making sulfuric acid; modern practice mostly recovers sulfur from smelter off-gas. Sulfur dioxide SO2, produced by burning sulfur or roasting pyrite, is used to make sulfites, pulp bleaching, food preservation, and wine stabilization, and is also a major air pollutant. Sodium thiosulfate Na2S2O3, commonly called hypo, is widely used in photographic fixing and in iodometric chemical analysis. Calcium sulfate CaSO4 is gypsum, used in building boards, as a cement set retarder, and as a coagulant in tofu making. Hydrogen sulfide H2S is used in natural gas sweetening and chemical analysis.

Element History

Known to antiquity — the ancient Egyptians used it for bleaching linen and making black gunpowder. First recognized as a distinct element in 1777 by Lavoisier, who included it in his list of simple substances recovered by chemical analysis. Modern production comes primarily from sulfur recovered as a byproduct of natural gas processing and petroleum refining, plus Frasch-process sulfur mining.

Alloys of this element (1)

View all alloys → ZnS

Related Elements

H · Hydrogen C · Carbon N · Nitrogen O · Oxygen P · Phosphorus Se · Selenium

Frequently Asked QuestionsLong-tail Q&A · data-driven

What is the melting point of Sulfur?
115 °C
What is the boiling point of Sulfur?
445 °C
What is the density of Sulfur?
2.07 g/cm³
What are the atomic number and category of Sulfur?
16 · Nonmetal
Which ore is Sulfur mainly extracted from?
native sulfur, pyrite
What are the main uses of Sulfur?
Sulfur is the 10th most abundant element in the universe and plays dual critical roles: as an essential component of proteins (disulfide bonds in cysteine) and as the feedstock for sulfuric acid — the single most importa
Who discovered Sulfur and when?
Ancient china · Ancient (known since antiquity)