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Lithium
Li 3

Lithium

Lithium (from Ancient Greek λίθος, líthos, 'stone') is a chemical element; it has symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable. The dominant use of lithium is in rechargeable lithium-ion batteries for electric vehicles, portable electronics, and grid-scale energy storage.

Alkali Metal USGS 2025 silvery-white
Atomic number 3Z
Atomic mass 6.94u
Valence e⁻ 1
Electron config. 1s2 2s1
Density
0.53g/cm³
Melting point
180°C
Crustal abundance
20.0ppm
Annual production
7240000metric tons
Recycling rate
5%(Emerging)

Why This Element

Lithium is the least dense metal on Earth (0.534 g/cm³) and possesses the most negative standard electrode potential of any element (-3.04 V). This combination enables an extraordinarily high specific energy — roughly three times that of nickel-based batteries — making lithium irreplaceable as the active metal in rechargeable battery chemistry for portable electronics, electric vehicles, and grid-scale energy storage.

Applications

Batteries
88%
Ceramics & glass
4%
Lubricating greases
2%
Air treatment
1%
Casting mold flux
1%
Pharmaceuticals
1%
Other
3%

Applications in DepthElement & compound uses

Main Uses of the Element

Lithium is the lightest metal in nature, with a density about half that of water, and it has become the most strategically coveted metal of the new-energy era. Its single largest use is as the core material of lithium-ion batteries: batteries in consumer electronics such as mobile phones, laptops and tablets rely almost entirely on lithium, while the large-format power batteries of electric vehicles and grid-scale energy storage stations have driven the rapid growth of global lithium demand, with a single electric-vehicle battery pack consuming on the order of ten kilograms of lithium. Beyond batteries, lithium-based greases withstand high temperatures and resist water well, and are widely used for long-life lubrication in automobiles, bearings and industrial machinery. In metallurgy, lithium is added as a deoxidizer and degasser to the melting of copper, aluminum and other metals to improve metal quality; adding lithium to glass and ceramics lowers the melting point and coefficient of thermal expansion, yielding heat-resistant cookware and low-expansion glass. In medicine, lithium carbonate is used to treat bipolar disorder (mania). Lithium is chosen for these applications because of its low atomic weight and low electrode potential, which let it store an extraordinarily high amount of electrical energy per unit mass—a property that few other metals can match.

Key Compounds and Their Uses

Lithium carbonate (Li2CO3) is the most basic lithium salt and the starting point for almost all lithium products, serving as the feedstock for battery cathode materials, lithium-salt purification and anti-manic pharmaceuticals. Lithium hydroxide (LiOH) is used mainly to manufacture lithium-based greases and is also an important raw material for high-nickel ternary cathode batteries; because it absorbs carbon dioxide strongly, it is also used for air purification in submarines and spacecraft. Lithium chloride (LiCl) is extremely hygroscopic and is used as a desiccant in industrial dehumidification and air-conditioning systems, as well as in molten-salt electrolysis to extract metallic lithium. Spodumene (LiAlSi2O6) is now one of the world's most important lithium ores; the hard-rock lithium mines in Australia and elsewhere mine it primarily, and it is processed by flotation, roasting and acid leaching to yield lithium carbonate, making it, alongside brine from salt lakes, one of the two principal sources of lithium. In addition, lithium bromide (LiBr), thanks to its strong water absorption, is widely used in absorption chillers of large central air-conditioning systems, and together with lithium chloride it forms another stable market for lithium salts in the HVAC industry.

Element History

Discovered in 1817 by Johan August Arfwedson while analyzing the mineral petalite (LiAlSi₄O₁₀). Isolated as the pure metal in 1855 via electrolysis. Large-scale production began in the 1920s from spodumene ores and evolved to include brine extraction starting in the 1960s.

Related Elements

Na · Sodium K · Potassium Rb · Rubidium Cs · Caesium Fr · Francium

Frequently Asked QuestionsLong-tail Q&A · data-driven

What is the melting point of Lithium?
180 °C
What is the boiling point of Lithium?
1330 °C
What is the density of Lithium?
0.53 g/cm³
What are the atomic number and category of Lithium?
3 · Alkali Metal
Which ore is Lithium mainly extracted from?
spodumene, brine
What are the world reserves of Lithium?
30000000 metric tons
What is the annual production of Lithium?
7240000 metric tons
What are the main uses of Lithium?
Lithium is the least dense metal on Earth (0.534 g/cm³) and possesses the most negative standard electrode potential of any element (-3.04 V). This combination enables an extraordinarily high specific energy — roughly th
Who discovered Lithium and when?
Johan August Arfwedson · 1817